Geology

wpe11.jpg (1383 octets)GAFSA Reactive Phosphate Rock, in short GAFSA RPR or GAFSA is a naturally occurring phosphate ore extracted by CPG from geological deposits formed in offshore marine conditions some 50 million years ago, a time when warm shallow lagoons covered the region. The deposits that are mined today are the result of a natural and slow geological process involving biological precipitation and sedimentation of phosphate with fossilized remains in the sea floor. The mined phosphate ore occurs in association with mineral and organic impurities, most of which are removed during beneficiation. The most common techniques used by CPG are washing, ventilation and flotation. 

Mineralogy-Reactivity

Gafsa phosphate rock was formed near the surface of the earth under low temperature and pressure conditions. Originated from primary marine phosphorites, it shows a microcrystalline structure. GAFSA phosphorites have a soft sandy texture and a high internal porosity.

GAFSA belongs to the francolite (carbonate-fluorapatite) group. This true mineral group is characterized by a chemical substitution that occurs naturally within the crystal structure of the phosphorite where some of carbonate groups (CO3) have replaced a phosphate group (PO4).

It is well known that a greater degree of carbonate substitution for phosphate in the apatite structure tends to make the PR more reactive when directly applied to the soil. Consequently, the apatite of reactive PRs has a greater ability to dissolve in the soil and to release available P to the plants then unreactive rocks.

According to standard solubility tests for reactivity assessment and various agronomic evaluations, GAFSA is classified by the international scientific community as one of the most reactive phosphates and most efficient natural P fertilizer in the world.

Specifications

CHEMICAL ANALYSIS ON DRY MATTER
Specifications Typical% Micronutrients Typical%
Phosphorus Pentoxide
P2O5 
28 - 29 Zinc 370 ppm
Sulfur Trioxide
SO3
3 - 4 Manganese 30 ppm
Carbon Dioxide
CO2
6.0 - 7.0 Cobalt 20 ppm
Total Silica
SiO2
2.5 - 3.6 Copper 19 ppm
Calcium Oxide
CaO
48 - 50 Molybdenium 50 ppm
Magnesium Oxide
MgO
0.6 - 0.7
 Iron Oxide
Fe2O3
0.3 - 0.4
Aluminum Oxide
Al2O3
0.4 - 0.6
Sodium Oxide
Na2O
1.2 - 1.4
Potassium Oxide
K2O
0.10 - 0.14
Fluorine
 F
3.0
Organic Carbon 1.0
Moisture (H2O) 3.0 max
SCREEN ANALYSIS
Undersize wt% minimum
Mesh, Tyler  32  (0.500 min) 90
Mesh, Tyler  60  (0.250 min) 75
Mesh, Tyler  80  (0.180 min) 60
Mesh, Tyler 100 (0.150 min) 50
SOLUBILITY
Method % of total P2O5 % of Rock
Ammonium Citrate (AOAC) 
Neutral Ammonium Citrate - 2nd extraction
Ammonium Citrate pH3
28 - 30
73 - 75
8 - 9
22 - 25
2% Citric Acid  
European Union
Others  (as received unground rock)
40 - 45
30 - 32
12 - 14
10 - 11
2% Formic Acid 
European Union
Others  (as received unground rock)
70 - 77
54 - 58
21 - 24
16 - 18

Gafsa P Fertilizer

wpe4.jpg (5018 octets)GAFSA is an efficient fertilizer providing significant amounts of phosphorus, calcium, and other vital nutrients required by plants and animals. These nutrients, taken out from the soil by plants, mainly in their ionic soluble compounds, are indispensable for their proper growth and development. It has a high rate of dissolution giving readily available phosphorus (P) for initial plant growth, combined with the advantages of the long-term residual effect. It increases the availability of other major nutrients such as N and K, and reduces micronutrient deficiency. It has a significant liming effect for acid soils and may constitute an alternative to liming in areas where minimal applications of lime are sufficient and lime is not available at an economic cost.

Unlike low reactive rocks that can present high CaO content but low available Ca, GAFSA appears to be an efficient source of Calcium with regard to plant nutrition and liming effect, not only because of its high CaO (45-50%), but most important, due to its high reactivity. Historically, fine grinding (200-300 Mesh Tyler sieve) was usually recommended for natural phosphate rocks in order to increase the surface area and hence the dissolution of the apatite. However countless research findings have established that fine grinding is not necessary for highly reactive PRs with particle size range of 50 to 60% passing a 100-mesh sieve. GAFSA responds to those criteria.

wpe5.jpg (6566 octets)GAFSA is a soft sedimentary phosphate with high internal porosity and a total surface area (unground state) even greater than that of other finely ground materials. For this reason, it is used in several countries of the world including United Kingdom, France, India, Indonesia, New Zealand, Australia and Brazil in its "as-received" state. Most of our customers acknowledge that grinding adds to the manufacturing cost of PR. When the rock is too fine, substantial amount of dust is noticeable which is extremely undesirable for loading and unloading operations. The product is also not suitable for mechanized application.

Since the beginning of the 20th century, GAFSA has been the focus of considerable interest from scientists throughout the world. Its agronomic advantages have been reported on a wide variety of crops and environments.

Statements from IFDC

In 1995 and 1999, GAFSA has been awarded two statements from IFDC (Alabama, USA), an International Scientific Institution. Those statements corroborate the data reported by eminent scientists throughout the world on its high reactivity and its fertilizer quality in direct application. 

 STATEMENT 1995 | STATEMENT 1999


History
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